Electronic structure and soft-X-ray-induced photoreduction studies of iron-based magnetic polyoxometalates of type {(M)M5}12FeIII30 (M = MoVI, WVI)
نویسندگان
چکیده
منابع مشابه
Electronic structure and soft-X-ray-induced photoreduction studies of iron-based magnetic polyoxometalates of type {(M)M5}12Fe(III)30 (M = Mo(VI), W(VI)).
Giant Keplerate-type molecules with a {Mo72Fe30} core show a number of very interesting properties, making them particularly promising for various applications. So far, only limited data on the electronic structure of these molecules from X-ray spectra and electronic structure calculations have been available. Here we present a combined electronic and magnetic structure study of three Keplerate...
متن کاملSoft X-ray Emission and Electronic Structure of Alloys
Soft X-ray band-emission data for solid binary solutions are reviewed, with particular reference to aluminium alloys, and their interpretation is discussed in relation to the rigid-band and virtual-bound-state models. The emission spectra only rarely support the rigid-band model. Measurements on alloys of the noble and transition metals with aluminium are interpreted in terms of virtual-bound o...
متن کاملElectronic structure of InN studied using soft x-ray emission, soft x-ray absorption, and quasiparticle band structure calculations
The electronic structure of wurtzite InN 0001̄ thin films has been studied using a combination of soft x-ray emission and absorption spectroscopies. We measured the elementally and orbitally resolved InN valence and conduction bands by recording the N K-edge spectra. Theoretical calculations of the N 2p partial density of states were performed within the GW framework of many body perturbation th...
متن کاملpostnatal studies of bats (pipistrellus kuhlii and miniopterus schreibersii) & histomorphology and histochemistry studies of organs and diseases of (neurergus microspilotus and n. kaiseri)
1. to determine whether difference in birth body mass influenced growth performance in pipistrellus kuhlii we studied a total of 12 captive-born neonates. bats were assigned to two body mass groups: light birth body mass (lbw: 0.89 ± 0.05, n=8) and heavy birth body mass (hbw: 1.35 ± 0.08, n=4). heavier body mass at birth was associated with rapid postnatal growth (body mass and forearm length) ...
ذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2013
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c3dt32759k